Perovskite solar cells are a promising next-generation photovoltaic technology that has gained significant attention in recent years. With their low-cost production, high efficiency, and versatility, perovskite solar cells have the potential to revolutionize the renewable energy sector. However, one of the challenges facing researchers is reducing energy losses within perovskite solar cells to maximize their overall efficiency.
Cobalt chloride hexahydrate (CoCl2·6H2O) is a chemical compound that has been widely used in various applications, including electroplating, humidity indicators, and as a catalyst in organic synthesis. In recent years, researchers have started exploring its potential in the field of perovskite solar cells due to its unique properties.
A group of researchers (Pengyang Wang et al.) have conducted research by introducing cobalt chloride hexahydrate into SnO2 thin films to improve the problems of defects and band structure. This study, published in ACS Energy Lett., marks a significant step forward in the quest for more efficient and stable perovskite solar cells.
The research demonstrates that the addition of cobalt chloride hexahydrate to the perovskite layer can effectively reduce energy losses caused by charge recombination. Charge recombination occurs when electrons and holes, generated by the absorption of light, recombine before being extracted as electrical current. This phenomenon leads to a decrease in the overall efficiency of the solar cell.
Below are the performance results of cobalt chloride hexahydrate modified SnO2 ETL:
l The SnO2-CoCl2 -based PSC exhibits a record-breaking voltage of 1.20 V (minimum energy loss of 0.34 V) and a champion PCE of 23.82%.
l The SnO2-CoCl2 -based PSC showed enhanced stability, maintaining an initial efficiency of 83.5% after 200 h under continuous irradiation.
l The SnO2-CoCl2 -based PSC retained 79.6% of their initial efficiency after 100 h at 60 °C in ambient air (relative humidity >50).
By adding cobalt chloride hexahydrate, Wang’s team observed a significant improvement in the power conversion efficiency of the perovskite solar cells. The compound acts as a passivation layer, preventing charge recombination and increasing the overall lifetime of the charge carriers. This results in a higher current output and a more efficient conversion of sunlight into electricity.
Moreover, cobalt chloride hexahydrate acts as a stabilizing agent, reducing the degradation of perovskite materials caused by moisture and heat. Perovskite solar cells are known to be sensitive to environmental factors, which can shorten their lifespan and reduce their efficiency. The addition of cobalt chloride hexahydrate enhances the stability of these cells, making them more durable and suitable for long-term use.
With continued advances in this technology, the widespread adoption of perovskite solar cells could soon become a reality, revolutionizing the renewable energy industry and mitigating the adverse effects of climate change. Alfa Chemistry's cobalt(II) chloride hexahydrate (CAS 7791-13-1) and cobalt(ii)chloride hydrate (CAS 69098-14-2) offers a cost-effective solution for improving the efficiency and stability of perovskite solar cells. With its unique properties, this compound has the potential to advance the development of this promising technology and accelerate the commercialization of perovskite solar cells. Perovskite solar cells offer increased efficiency and cost-effectiveness compared to traditional silicon-based cells. Alfa Chemistry also provides high-quality perovskite precursor materials, such as lead iodide, methylammonium iodide, and various other organic and inorganic compounds required for the production of these cells.
